At. Voutsas et al., STRUCTURE ENGINEERING FOR HILLOCK-FREE PURE ALUMINUM SPUTTER-DEPOSITION FOR GATE AND SOURCE LINE FABRICATION IN ACTIVE-MATRIX LIQUID-CRYSTAL DISPLAYS, Journal of vacuum science & technology. A. Vacuum, surfaces, and films, 16(4), 1998, pp. 2668-2677
Citations number
27
Categorie Soggetti
Physics, Applied","Materials Science, Coatings & Films
In this article we present the results of a study aimed at developing
hillock-free, pure-Al thin-film material suitable for the fabrication
of gate and source lines in thin film transistor active-matrix liquid
crystal displays. Strong Al(111) texture was shown to be a key attribu
te for achieving good resistance to hillock formation. To obtain this
strong Al(111) texture, we explored the incorporation of a thin metal
layer, under the Al film, and we showed that Ti could be an appropriat
e candidate for further optimization. Key variables affecting the qual
ity of Al were found to be the roughness of the glass substrate, the t
hickness of the titanium, the background vacuum quality, and the sputt
ering temperature. By optimizing the deposition process for both Al an
d Ti layers, we showed that aluminum films with very strong (111) text
ure (rocking curve full width at half maximum 0.86 degrees), very smoo
th surface (root mean square surface roughness 1.8 nm), and a uniform,
columnar grain size (0.3-0.5 mu m) could be deposited by de magnetron
sputtering. In addition to improving the aluminum microstructure, opt
imization of the gate dielectric process was also performed with the a
im of reducing hillock formation. Combined optimization of the sputter
ing and gate dielectric deposition processes yielded an overall reduct
ion in hillock density of 3.5-4 orders of magnitude, without the need
for anodic oxidation or other means of capping the aluminum film. By c
ombining Al/Ti de sputtering, dry-etching technology for one-step patt
erning of the composite Al/Ti film, and gate insulator deposition at 3
00 degrees C we demonstrated, for the first time, gate metallization t
echnology based on pure Al with excellent step coverage and ultralow h
illock density (< 10(3) cm(-2)). (C) 1998 American Vacuum Society. [S0
734-2101(98)03004-8].