A small portion of a monolayer of pre-deposited carbon on Si (100) cau
ses Ge island formation after epitaxial growth of less than two monola
yers (ML) Ge. The epitaxial growth is done in a solid source MBE syste
m. The carbon-induced Ge quantum dots can be as snail as 10 nm in late
ral size and 1 to 2 nm in height. The area density is about 1 x 10(11)
cm(-2). Pure Ge on Si forms large dots of about 100 nm in lateral siz
e. Compared to Si/SiGe quantum wells and neighboring Si1-xGex/Si1-yCy
quantum wells we observe very intensive photoluminescence (PL) signal
from such small Ge dots. Varying the C and Ge deposition reveals a dis
tinct PL intensity maximum for 0.2 ML C followed by about 2.2 ML Ge. W
e propose a spatially indirect radiative recombination mechanism. Vert
ical stacking of the C-induced Ge dots results in strongly increased P
L intensity and red shifted transition energy. (C) 1998 Published by E
lsevier Science Ltd. All rights reserved.