Y. Kariya et M. Otsuka, EFFECT OF BISMUTH ON THE ISOTHERMAL FATIGUE PROPERTIES OF SN-3.5MASS-PERCENT-AG SOLDER ALLOY, Journal of electronic materials, 27(7), 1998, pp. 866-870
Sn-3.5mass%Ag eutectic solder is selected as a candidate base alloy fo
r replacing the eutectic Sn-Pb, and the effect of bismuth (2, 5, 10mas
s%) on the fatigue Life of bulk Sn-3.5mass%Ag eutectic at room tempera
ture has been studied over the total strain range from 0.3 to 3 percen
t in tension-tension mode. Fatigue life is defined as the number of cy
cles at which the load decreases to a half of the initial value. The f
atigue Life dramatically decreases with increasing contents of bismuth
and adding this element over 2% makes fatigue life shorter than that
of tin-lead eutectic alloy. Tensile strength of the alloy significantl
y increases with an increase in bismuth contents due to solid solution
hardening (<5%Bi) or dispersion strengthening of fine bismuth particl
es, while ductility of this system dramatically decreases with increas
ing bismuth contents. Fatigue life of these alloys depends on ductilit
y obtained by tensile test. The fatigue life of Bi containing Sn-3.5%A
g alloys can be described by (Delta epsilon(p)/2D).N-f( 0.59) = 0.66 w
here N-f is fatigue Life defined by number of cycles to one-half load
reduction, Delta epsilon(p) is the plastic strain range for initial cy
cles, D is the ductility as measured by reduction in area.