S. Lian et al., PHOTO-ENHANCED CHEMICAL-VAPOR-DEPOSITION - SYSTEM-DESIGN CONSIDERATIONS, Journal of vacuum science & technology. A. Vacuum, surfaces, and films, 11(6), 1993, pp. 2914-2923
ArF excimer laser-enhanced photochemical vapor deposition of Si from S
i2H6 in an UHV deposition chamber has been used to achieve Si epitaxy
at temperatures as low as 250-degrees-C. The system design criteria ar
e discussed. Modified Schimmel etching/Nomarski microscopy, transmissi
on electron microscopy, and reflection high energy electron diffractio
n have been used to study the microstructure of Si films as a function
of laser power, substrate temperature and disilane partial pressure.
The growth rates were observed to be linearly dependent on laser inten
sity and Si2H6 partial pressure. The morphology of the films is excell
ent and defects such as dislocation loops and stacking faults are not
seen.