C. Falcony et al., HIGH-QUALITY, HIGH DEPOSITION RATE SIO2-FILMS AT LOW-TEMPERATURES USING SILICON FLUORIDES AND PLASMA-ASSISTED DEPOSITION TECHNIQUES, Journal of vacuum science & technology. A. Vacuum, surfaces, and films, 11(6), 1993, pp. 2945-2949
High quality SiO2 films have been deposited by the plasma enhanced che
mical vapor deposition technique using SiF4 and N2O. It has been deter
mined that a small amount of hydrogen is needed to reduce the amount o
f residual fluorine atoms in the oxide improving the structural and el
ectrical properties of the film. Using SiH4 as a source of hydrogen in
stead of H-2 results in a high deposition rate increasing from 7 to mo
re than 500 A/min depending on the total content of SiH4. However, for
the high deposition rates studied, hydrogen related impurities start
to appear and some degradation of the electrical characteristics of th
e films are observed.