We have studied by electron probe microanalysis (EPMA) the growth of t
hin surface layers prepared by evaporation and have compared the exper
imental k(d) curves before and after heating the samples with those ca
lculated by Monte Carlo simulation. When studying systems of substrate
and layer materials forming homogeneous flat films, the correspondenc
e of the experimental and calculated k(a) curves (the normalized inten
sities of the characteristic x-ray lines of film and substrate materia
l, depending on film thickness d) is quite good. However, when forming
alloys of these materials, for example by heating the sample, the exp
erimental k(d) curve is drastically changed.