Sh. Brongersma et al., EQUILIBRIUM SHAPE OF COSI2 HUT CLUSTERS ON SI(100), Journal of vacuum science & technology. B, Microelectronics and nanometer structures processing, measurement and phenomena, 16(4), 1998, pp. 2188-2190
CoSi2 clusters of constant height on a Si(100) surface grow in a squar
e shape at first, but at a critical size a shape transition to cluster
s with large aspect ratios occurs. With each cluster connected to an i
mplanted layer of cobalt by a thermally induced defect that serves as
a diffusion channel, clusters can grow independently with a continuous
supply of cobalt. When the cobalt supply is limited, clusters grow up
to a specific volume and then have time to adjust their height, assum
ing their minimum-energy shape. Although calculations indicate that th
is should be a square pyramid, experiments indicate that a more elonga
ted cluster corresponds to equilibrium. (C) 1998 American Vacuum Socie
ty.