Ke. Smith et al., SOFT-X-RAY EMISSION STUDIES OF THE BULK ELECTRONIC-STRUCTURE OF ALN, GAN, AND AL0.5GA0.5N, Journal of vacuum science & technology. B, Microelectronics and nanometer structures processing, measurement and phenomena, 16(4), 1998, pp. 2250-2253
The electronic structure of wurtzite GaN, Al0.5Ga0.5N, and AlN has bee
n studied using synchrotron radiation excited soft x-ray emission spec
troscopy. In particular, the elementally resolved partial densities of
states has been measured and found to agree well with calculations. T
he shift in energy of the valence band maximum as x varies from 0 to 1
in AlxGa1-xN was measured by recording N K-emission spectra, and foun
d to be linear. Furthermore, N K-emission spectra revealed resonantlik
e hybridization of N 2p and Ga 3d states at 19 eV below the GaN valenc
e band maximum. The spectral intensity of this feature is proportional
to Ga content. (C) 1998 American Vacuum Society.