A. Schneuwly et al., INFLUENCE OF SURFACE CONTAMINATION ON METAL METAL BOND CONTACT QUALITY/, Journal of electronic materials, 27(8), 1998, pp. 990-997
The influence of surface cleanliness of Au/Ni coated multichip materia
ls (MCMs), Ag plated Cu lead frames, and Al bond pads on semiconductor
chips ion the strength of Au wire bond contacts has been investigated
. A clean surface is important for good adhesion in any kind of attach
ment process. Investigations by means of x-ray photoelectron spectrosc
opy have been Performed on the bond substrates to determine the chemic
al composition, the nature as well as the thickness of the contaminati
on layer. The influence of contamination on bond contact quality has b
een examined by pull force measurements, which is an established test
method in semiconductor packaging industry for evaluating the quality
of wire bonds. The results clearly show that a strong correlation betw
een : the degree of contamination of the substrate and pull strength v
alues exists. Furthermore, a contamination thickness limiting value of
4 nm for Au and Ag substrates was determined, indicating good wire bo
nd contact quality. The effect of plasma cleaning on wire bondability
of metallic and organic (MCMs) substrates has been examined by pull fo
rce measurements. These results confirm the correlation between surfac
e contamination and the strength of wire bond contacts for Au/Ni coate
d MCMs and Ag plated Cu lead frames. Atomic force microscopy measureme
nts have been performed to determine the roughness of bond surfaces, d
emonstrating the importance of nanoscale characterization with regard
to the bonding behavior of the substrates. Finally, bonding substrates
used in integrated circuit packaging are discussed with regard to the
ir Au wire bonding behavior. The Au wire bonding process first results
in a cleaning effect of the substrate to be joined and secondly enabl
es the change of bonding energy into frictional heat giving rise to an
enhanced interdiffusion at; the interface.