T. Kagawa et al., EFFECTS OF INTERMEDIATE SEMICONDUCTOR LAYERS ON CARRIER TRANSPORT MECHANISMS THROUGH P-ZNSE METALS INTERFACES/, Journal of electronic materials, 27(8), 1998, pp. 998-1002
The effects of formation of intermediate semiconductor layers at p-ZnS
e/metals interfaces on carrier transport mechanisms were studied by co
mparing contacts prepared by the deposition and annealing (DA) techniq
ue or the molecular beam epitaxy (MBE) technique. Current density vs v
oltage (J-V) curves of the MBE contact with a p-ZnSe/p-ZnTe superlatti
ce intermediate layer showed ohmic behavior. However, J-V curves of th
e DA contact with a ZnTe intermediate layer showed rectifying behavior
. The difference of the electrical properties: between these two conta
cts was due to existence of a highly resistive intermediate layer with
highly dense defects in the DA contact and a low resistance,p-type co
nductive intermediate layer with relatively small densities of crystal
line defects in the MBE contacts. From the present results, it was con
cluded that formation of the highly resistive semiconductor layer with
dense crystalline defects prevented the DA contact to transit from no
n-ohmic J-V behavior to ohmic.