We report on the growth of high structural quality (as determined by x
-ray diffraction) GaN on a near lattice matched substrate, lithium gal
late (LiGaO2 or LGO). Low;temperature growth conditions are described
that result in very thin GaN films (<0.3 mu m) with (0004) x-ray diffr
action rocking curves full width at half maximum (FWHM) of 145 are-sec
and thicker films (I mu m) resulting in 85 arcsec FWHM, The effect of
growth temperature is examined and found to result in a broad minimum
in x-ray FWHM around 690 degrees C. Detailed growth conditions and de
scriptions of the reflection high energy electron diffraction patterns
observed during growth are given. Additionally, we report very highly
resistive material and doped material with bulk electron mobilities i
n excess of 100 cm(2)/V-sec.