Qx. Xu et Cm. Hu, NEW TI-SALICIDE PROCESS USING SB AND GE PREAMORPHIZATION FOR SUB-O.2 MU-M CMOS TECHNOLOGY, I.E.E.E. transactions on electron devices, 45(9), 1998, pp. 2002-2009
A new process for thin titanium self-aligned silicide (Ti-SALICIDE) on
narrow n(+) poly-Si lines and n(+) diffusion layers using preamorphiz
ation implantation (PAI) with heavy ions of antimony (Sb) and germaniu
m (Ge) has been demonstrated for application to 0.2-mu m CMOS devices
and beyond. Preamorphization enhances the phase transformation from C4
9TixSix to C54TiSi2 and lowers the transformation temperature by 80 de
grees C so that it occurs before conglomeration in narrow lines. Pream
orphization by Sb and Ge implantation yields better results than that
by As. The sheet resistance of TiSi2 on heavily As doped poly-Si lines
are 3.7 Omega/square and 3.8 Omega/square for the samples preamorphiz
ed by Ge and Sb implantations even with line width down to 0.2 mu m. T
here is less leakage in the Ti-SALICIDE diode with preamorphization th
an without it. The probable reasons and mechanisms are discussed.