Da. Evans et al., OVERLAYER-INDUCED VALENCE STATES, AND EVIDENCE FOR CHARGE-TRANSFER INNA GAP(110) AND NA/GAAS(110) - A COMPARATIVE PHOTOEMISSION-STUDY/, Journal of vacuum science & technology. B, Microelectronics and nanometer structures processing, measurement and phenomena, 11(4), 1993, pp. 1492-1496
Core and valence level photoemission experiments for Na overlayers on
GaP(110) and GaAs(110) reveal new peaks which are interpreted in terms
of Na-Ga charge transfer, as predicted by total energy calculations.
New peaks in the region above the valence band are identified with the
previously empty Ga surface state which is filled by the charge trans
fer process. The role of this gap emission in the pinning of the Fermi
level at submonolayer to metallic coverages is discussed for both sem
iconductors.