Ck. Campbell et al., DEVELOPMENT OF LARGE-AREA BATIO3 CERAMICS WITH OPTIMIZED DEPLETION REGIONS AS DIELECTRICS FOR PLANAR POWER ELECTRONICS, IEEE transactions on components, packaging, and manufacturing technology. Part A, 21(3), 1998, pp. 492-499
High-voltage (500 V) barium titanate (BaTiO3) ceramics are under devel
opment as compact high-permittivity dielectrics for planar structures
in integrated power-electronic converters. Dielectric requirements inc
lude a high permittivity for meeting the dimensional constraints in co
nverters, a high power-handling capability, low loss, and flat permitt
ivity and tan delta frequency responses up to 1 MHz. Dopant materials
examined here focused on fine powders of Al2O3 and Al added during the
sintering process. Best results were obtained by diffusion of externa
lly-placed Al during the sintering cycle, with BaTiO3 permittivities e
psilon(r) similar to 1000, and loss tangents tan delta similar to 4% o
ver 1 kHz to 1 MHz. This paper describes fabrication and doping method
s aimed at achieving such specifications. Electrical C-V testing up to
500 V on specimens of thickness 0.5-0.7 mm (with E-field intensities
up to 10(6) V/m) was carried out using 1-kHz bridge measurements, as w
ell as in a power-electronic chopper circuit employing a BJT switch, a
nd operating up to 500 V with pulse widths similar to 25 mu s and repe
tition rates similar to 4 kHz.