In. Mihailescu et al., EXCIMER-LASER REACTIVE ABLATION - AN EFFICIENT APPROACH FOR THE DEPOSITION OF HIGH-QUALITY TIN FILMS, Journal of vacuum science & technology. A. Vacuum, surfaces, and films, 11(5), 1993, pp. 2577-2582
The successful deposition of TiN films on Si wafers by excimer (lambda
=308 nm) multipulse laser ablation of Ti in a low pressure N2 jet is r
eported in this article. The films are particularly pure, entirely con
sisting of polycrystalline fcc TiN. One difficulty still seems to be r
elated to the presence of small droplets probably ejected in a liquid
phase. According to the analyses, TiN is formed on Ti target with smal
l contributions only, if any, of the next transit through gas and fina
l deposition onto the Si wafer support.