R. Bruchhaus et al., PZT THIN-FILMS GROWN BY MULTITARGET SPUTTERING - ANALYSIS OF THIN-FILM STRESS, Integrated ferroelectrics (Print), 21(1-4), 1998, pp. 461-467
A planar multi target sputtering approach was used to deposit Pb(Zr,Ti
)O-3 (PZT) films with different composition on Pt bottom electrodes fo
r the use in thin film pyroelectric IR detector arrays. Low stress fer
roelectric capacitor stacks are needed in these devices, because the s
ensing elements are arranged on thin micromachined membranes. PZT film
s with a Zr content of 10 at% (10/90) and 48 at% (48/52) were analyzed
in terms of thin film stress. PZT (10/90) films were found in a sligh
t compressed state and PZT (48/52) under tensile stress after depositi
on. Stress temperature curves were used to evaluate the Curie temperat
ure of the films. From the stress temperature curves the spontaneous d
istortion of the ferroelectric given by the lattice parameters can be
extracted. The lower Curie temperature in combination with the smaller
spontaneous distortion of the PZT (48/52) film is the reason for the
difference in the stress state after deposition.