T. Ushiki et al., IMPROVEMENT OF GATE OXIDE RELIABILITY FOR TANTALUM-GATE MOS DEVICES USING XENON PLASMA SPUTTERING TECHNOLOGY, I.E.E.E. transactions on electron devices, 45(11), 1998, pp. 2349-2354
The effects of ion species in sputtering deposition process on gate ox
ide reliability have been experimentally investigated. The use of xeno
n (Xe) plasma instead of argon (Ar) plasma in tantalum (Ta) film sputt
ering deposition for gate electrode formation makes it possible to imp
rove the gate oxide reliability. The,Ye plasma process exhibits 1.5 ti
mes higher breakdown field and five times higher 50 %-charge-to-breakd
own (Q(BD)) In the Ta sputtering deposition process on gate oxide, the
physical bombardment of energetic inert-gas ion causes to generate ho
le trap sites in gate oxide, resulting in the lower gate oxide reliabi
lity. The simplified model providing a better understanding of the emp
irical relation between the gate oxide damage and the inert-gas ion bo
mbardment energy in gate-Ta sputtering deposition process is also pres
ented.