Twenty-one compounds, which had been screened in preceding experiments
as potent odorants of french fries prepared in palm oil (PO), were qu
antified by stable isotope dilution assays. Nineteen odorants were dis
solved in sun flower oil in concentrations equal to those in PO. The f
avor profile of the model obtained was close to that of a real sample
of PO. A comparison of the complete model with models lacking one or m
ore compounds indicated the following key odorants of PO: 2-ethyl-3,5-
dimethylpyrazine, 3-ethyl-2,5-dimethylpyrazine, 2,3-diethyl-5-methylpy
razine, 3-isobutyl-2-methoxypyrazine, (E,Z)- and (E,E)-2,4-decadienal,
trans-4,5-epoxy-(E)-2-decenal, 4-hydroxy-2,5-dimethyl-3(2H)-furanone,
methylpropanal, 2- and 3-methylbutanal, and methanethiol. Replacement
of palm oil by coconut fat led to a coconut note in the profile of Fr
ench fries. gamma-Octalactone was identified as a major contributor to
this note.