In this work, free-standing GaN single crystalline crackless substrate
s were grown by hydride vapor phase epitaxy (HVPE). The GaN substrate,
having a current maximum size of 350 mu m thickness and 10 mm x 10 mm
area, were obtained by the HVPE growth of a thick-film GaN on a sapph
ire substrate. Subsequently, the sapphire substrate was removed. To gr
ow the crack-free GaN on a sapphire substrate, cracks were intentional
ly generated only in the sapphire substrates after 100 mu m thickness
GaN growth, and then the GaN thick film was re-grown. The GaN single c
rystalline substrate prepared through this work was found to be optica
lly and electrically superior to those of bulk GaN single crystals. Th
e free-standing and crack-free GaN single crystalline substrate is sui
table for the homoepitaxial growth of GaN. (C) 1998 Elsevier Science B
.V. All rights reserved.