PSEUDOHALOGENATION OF METHYL 9-HYDROXY-CIS-12-OCTADECENOATE AND 12-HYDROXY-CIS-9-OCTADECENOATE

Authors
NAQVI F RAUF A SIDDIQUI MM AHMAD MS OSMAN SM
Citation
F. Naqvi et al., PSEUDOHALOGENATION OF METHYL 9-HYDROXY-CIS-12-OCTADECENOATE AND 12-HYDROXY-CIS-9-OCTADECENOATE, Journal of the American Oil Chemists' Society, 74(6), 1997, pp. 713-717
Citations number
16
Categorie Soggetti
Food Science & Tenology","Chemistry Applied
Journal title
Journal of the American Oil Chemists' Society → ACNP
ISSN journal
0003021X
Volume
74
Issue
6
Year of publication
1997
Pages
713 - 717
Database
ISI
SICI code
0003-021X(1997)74:6<713:POM9A1>2.0.ZU;2-G
Abstract
Pseudohalogenation of methyl 9-hydroxy-cis-12-octadecenoate (I) and me thyl 12-hydroxy-cis-9-octadecenoate (II) has been carried out with N,N -dibromobenzenesulfonamide (NNDBS). Compounds I and II, on reaction wi th NNDBS, formed four and three products, respectively. The interestin g feature of these reactions was the formation of 1,4-epoxy compounds. The structures of individual compounds were established with the help of elemental and spectral analysis.