I. Colera et al., ELECTRON-STIMULATED DESORPTION STUDY OF THE MGO(100)-D2O SYSTEM, Journal of vacuum science & technology. A. Vacuum, surfaces, and films, 15(3), 1997, pp. 1698-1703
Citations number
23
Categorie Soggetti
Physics, Applied","Materials Science, Coatings & Films
A study of the MgO(100)-D2O system at 300 K by electron stimulated des
orption (ESD) over the energy range up to 600 eV is presented. Auger e
lectron spectroscopy is used as a complementary technique. ESD of the
nearly perfect clean surface shows O+ desorbed ions as the main desorb
ed species with small amounts of H+ and F+ contaminants. The adsorptio
n of D2O produces a dramatic decrease of the O+ intensity in the ESD s
pectrum and new signals corresponding to D+ and OD+ ions are observed.
There is a first energy threshold at about 30 eV for D+ and H+ desorb
ed ions and a second one at 55 eV for O+ desorbed ions. The desorption
of these ions corresponds to a primary excitation of the O 2s (24 eV)
and Mg 2p (55 eV) core levels, respectively. The ion kinetic energy d
istribution of the desorbed O+ ion from the clean surface has two peak
s at energies of 6 and 9 eV. The ion kinetic energy distribution of th
e D+ desorbed ions also shows a bimodal structure with most probable k
inetic energies of 3 and 6.5 eV at 150 eV incident electron energy. Th
e ion kinetic energy distribution of the H+ desorbed ions from the H c
ontamination correlates quite well with that of the D+ desorbed ions b
oth in shape and in energy. The most probable kinetic energy of the OD
+ is about 3 eV. From these experiments, we propose an adsorption mode
l with the D2O dissociated as OD+D. The D species bonds to O surface i
ons to form OsurfD radicals, and the OD species bonds to Mg surface io
ns. Since the experiments were performed at D2O constant pressure ther
e is a large increase of the D+ intensity due to ESD of the D from OB
species. The final equilibrium of the adsorbed species is a consequenc
e of the D2O adsorption and ESD desorption rates. (C) 1997 American Va
cuum Society.