Crystalline Bi1.8Pb0.2Sr2Ca2Cu3O10+x films deposited at substrate temp
eratures t(s) from 400 to 700 degrees C were characterized by x-ray di
ffraction, optical absorption, and resistivity measurements. The effec
t of t(s) on film structure and the role of different atomic arrangeme
nts in metallic conduction are examined. The nonmonotonic dependence o
f the physical properties of the films on substrate temperature is att
ributed to a second-order phase transition at t(s) similar or equal to
600 degrees C associated with structural ordering.