The equilibrium composition-p(O2) diagram at 1270 K is mapped out, and
the temperature dependence of p(O2) for a number of (Li0.5Fe2.5O4)(x1
) (Cu0.5Fe2.5O4)(x2) (CuFe2O4)(1-x1-x2) spinel solid solutions at the
low-oxygen boundary of the stability held is determined. A general rel
ationship between oxygen pressure and temperature is obtained for the
entire range of solid solutions, which enables one to synthesize desir
ed compositions.