Mv. Shankar et Kbr. Varma, PIEZOELECTRICALLY STIMULATED DIELECTRIC-DISPERSION IN KAP SINGLE-CRYSTALS, Materials chemistry and physics, 49(1), 1997, pp. 78-82
The frequency response of the dielectric constant (epsilon(r)), the lo
ss tangent (tan delta) and impedance Z of potassium acid phthalate (KA
P) single crystals, monitored along the polar axis, exhibit strong res
onances in the frequency range 50-200 kHz, depending on the dimensions
of the sample. The observed resonance effect, which is strongly depen
dent on the geometric shape and size of the sample, is attributed to i
ts piezoelectric nature. The resonance peak positions have been monito
red as a function of both temperature and uniaxial pressure. The stiff
ness coefficient (C), computed based on the resonance data, is found t
o decrease with increasing temperature and increase with increasing pr
essure. The electro-mechanical coupling coefficient (k), obtained by r
esonance-anti-resonance method, has also been found to increase with r
ise in temperature. The epsilon(r) behaviour along the polar axis, as
a function of temperature is consistent with that of k. The preliminar
y results on the influence, of partial replacement of K+ ions in the K
AP crystal by Cs+ and Li+ ions, on the observed piezoelectric resonanc
e effects are also included.