Wmb. Duval et al., PHYSICAL VAPOR TRANSPORT OF MERCUROUS CHLORIDE CRYSTALS - DESIGN OF AMICROGRAVITY EXPERIMENT, Journal of crystal growth, 174(1-4), 1997, pp. 120-129
Flow field characteristics predicted from a computational model show t
hat the dynamical state of the flow, for practical crystal growth cond
itions of mercurous chloride, can range from steady to unsteady. Evide
nce that the flow field can be strongly dominated by convection for,gr
ound-based conditions is provided by the prediction of asymmetric velo
city profiles by the model which show reasonable agreement with laser
Doppler velocimetry experiments in both magnitude and planform. Unstea
dy flow is shown to be correlated with a degradation of crystal qualit
y as quantified by light scattering pattern measurements. A microgravi
ty experiment is designed to show that an experiment performed with pa
rameters which yield an unsteady Bow becomes steady (diffusive-advecti
ve) in a microgravity environment of 10(-3)g(0) as predicted by the mo
del; and hence yields crystals with optimal quality.