CONDUCTOMETRIC INVESTIGATIONS OF ZIRCONYL SOAPS IN A XYLENE-METHANOL MIXTURE

Citation
Kn. Mehrotra et M. Anis, CONDUCTOMETRIC INVESTIGATIONS OF ZIRCONYL SOAPS IN A XYLENE-METHANOL MIXTURE, Journal of the American Oil Chemists' Society, 74(7), 1997, pp. 775-779
Citations number
10
Categorie Soggetti
Food Science & Tenology","Chemistry Applied
ISSN journal
0003021X
Volume
74
Issue
7
Year of publication
1997
Pages
775 - 779
Database
ISI
SICI code
0003-021X(1997)74:7<775:CIOZSI>2.0.ZU;2-P
Abstract
Conductometric measurements of solutions of zirconyl soaps in xylene-m ethanol (4:1, vol/vol) mixture were carried out at 30-50 degrees C, an d the results were used to determine the degree of ionization, ionizat ion constant, and various thermodynamic parameters for both ionization and association processes. The results show that the soaps behave as weak electrolytes in dilute solutions, and the concentrations at which aggregation commences increased with increasing temperature and decre asing chainlength of the soap molecules.