Sw. Ryu et al., REDUCTION OF AS CARRYOVER BY PH3 OVERPRESSURE IN METALORGANIC VAPOR-PHASE EPITAXY, Journal of crystal growth, 179(1-2), 1997, pp. 26-31
InGaAs/InP superlattices were grown to analyze the As carryover at the
InP-on-InGaAs interface in metalorganic vapor-phase epitaxy. The anal
ysis through the double crystal X-ray diffractometry and the subsequen
t simulation revealed that a InAsP transient layer is formed at the in
terface due to As carryover to the InP layer. The change of PH3 flow r
ate during the growth interruption is found to be effective in control
ling the desorption of As from the deposits on the reactor wall. It is
believed that the increase of PH3 flow rate accelerates the As desorp
tion and thus the As depletion is completed in a shorter time. In addi
tion, the increased amount of desorbed As helps to protect the InGaAs
surface during PH3 flow. The high PH3 flow and the corresponding inter
ruption time provide nearly As-free InP-on-InGaAs interface.