REDUCTION OF AS CARRYOVER BY PH3 OVERPRESSURE IN METALORGANIC VAPOR-PHASE EPITAXY

Citation
Sw. Ryu et al., REDUCTION OF AS CARRYOVER BY PH3 OVERPRESSURE IN METALORGANIC VAPOR-PHASE EPITAXY, Journal of crystal growth, 179(1-2), 1997, pp. 26-31
Citations number
11
Categorie Soggetti
Crystallography
Journal title
ISSN journal
00220248
Volume
179
Issue
1-2
Year of publication
1997
Pages
26 - 31
Database
ISI
SICI code
0022-0248(1997)179:1-2<26:ROACBP>2.0.ZU;2-I
Abstract
InGaAs/InP superlattices were grown to analyze the As carryover at the InP-on-InGaAs interface in metalorganic vapor-phase epitaxy. The anal ysis through the double crystal X-ray diffractometry and the subsequen t simulation revealed that a InAsP transient layer is formed at the in terface due to As carryover to the InP layer. The change of PH3 flow r ate during the growth interruption is found to be effective in control ling the desorption of As from the deposits on the reactor wall. It is believed that the increase of PH3 flow rate accelerates the As desorp tion and thus the As depletion is completed in a shorter time. In addi tion, the increased amount of desorbed As helps to protect the InGaAs surface during PH3 flow. The high PH3 flow and the corresponding inter ruption time provide nearly As-free InP-on-InGaAs interface.