The contents of butanoic, 2-methylpropanoic, pentanoic, (S)-2-methyl-b
utanoic and 3-methylbutanoic acids have been determined in several pai
rs of steam treated and not treated samples of medium roasted coffee b
y capillary gas chromatography after preparing an infusion with hot wa
ter and clean-up by precipitation with methanol, freeze-drying and sim
ultaneous distillation/extraction (SDE). Contents of the treated sampl
es are lower in most cases. For detection of steam treatment, 3-methyl
butanoic acid and, in the second place, (S)-2-methylbutanoic acid are
suited best, because in every case their contents are lowered by treat
ment, and because the reductions are more pronounced than those of the
other acids.