During storage for four days at 4 degrees C of pre-cooked minced pork,
lipid oxidation measured as thiobarbituric acid reactive substances (
TBARS) and as hexanal by solid phase microextraction was found to depe
nd on the level of lipid hydroperoxides rather than on the TBARS in th
e raw muscle (M. Longissimus dorsi). Storage for up to six days at 4 d
egrees C, prior to mincing and cooking, resulted in a decrease in lipi
d hydroperoxides measured as conjugated dienes and in increasing TBARS
-value in the raw muscle, and in a pre-cooked product with better oxid
ative stability. The correlation coefficient between accumulation of T
B TBARS and hexanal in the pre-cooked meat was 0.98, indicating that t
he new technique using solid phase microextraction with subsequent GC-
analysis for determination of hexanal can be used as an alternative te
chnique to describe lipid oxidation in pre-cooked meat. (C) 1997 Elsev
ier Science Ltd.