THERMODYNAMICS OF CAO-SIO2 AND MNO-SIO2 MELTS .2. THERMODYNAMIC MODELING AND PHASE-EQUILIBRIUM CALCULATIONS

Authors
ZAITSEV AI MOGUTNOV BM
Citation
Ai. Zaitsev et Bm. Mogutnov, THERMODYNAMICS OF CAO-SIO2 AND MNO-SIO2 MELTS .2. THERMODYNAMIC MODELING AND PHASE-EQUILIBRIUM CALCULATIONS, Inorganic materials, 33(8), 1997, pp. 823-831
Citations number
41
Categorie Soggetti
Material Science
Journal title
Inorganic materials → ACNP
ISSN journal
00201685
Volume
33
Issue
8
Year of publication
1997
Pages
823 - 831
Database
ISI
SICI code
0020-1685(1997)33:8<823:TOCAMM>2.0.ZU;2-W
Abstract
A thermodynamic model is proposed for describing silicate melts in the associated solution approximation with allowance made for the formati on of various silicon-oxygen groups. The model predicts the compositio n and temperature dependences of the thermodynamic properties in the C aO-SiO2 and MnO-SiO2 melt systems with an accuracy comparable to the e xperimental error and adequately describes phase equilibria in these s ystems. The thermodynamic parameters of silica polymerization are foun d to be independent of the silicate melt.