ATOMIC-FORCE MICROSCOPE AND SCANNING TUNNELING MICROSCOPE STUDIES OF SUPERLATTICES AND DENSITY WAVES IN FE DOPED NBSE2, TASE2, TAS2 AND IN NBSE3 DOPED WITH FE, CO, CR, AND V
Rv. Coleman et al., ATOMIC-FORCE MICROSCOPE AND SCANNING TUNNELING MICROSCOPE STUDIES OF SUPERLATTICES AND DENSITY WAVES IN FE DOPED NBSE2, TASE2, TAS2 AND IN NBSE3 DOPED WITH FE, CO, CR, AND V, Journal of vacuum science & technology. B, Microelectronics and nanometer structures processing, measurement and phenomena, 12(3), 1994, pp. 1801-1804
Results of atomic force microscope (AFM) and scanning tunneling micros
cope (STM) studies of superlattices and long-range modulations induced
by impurities in transition metal chalcogenides are presented. Superl
attices formed by Fe intercalation into the van der Waals gaps of 2H-N
bSe2, 2H-TaSe2 and 2H-TaS2 show ordered occupation of the octahedral h
oles and STM spectroscopy shows density-wave energy gaps existing in t
he antiferromagnetic phases. In NbSe3, interstitial impurities such as
Fe, Co, Cr, and V induce long-range modulated structures that can be
detected at room temperature with AFM scans. These modulations modify
the charge-density wave structure forming at low temperature and STM s
pectroscopy has been used to measure these changes.