A. Manivannan et al., SCANNING-TUNNELING-MICROSCOPY AND SPECTROSCOPY OF MOS(2) THIN-FILMS PREPARED BY AN INTERCALATION EXFOLIATION METHOD, Journal of vacuum science & technology. B, Microelectronics and nanometer structures processing, measurement and phenomena, 12(3), 1994, pp. 2111-2114
Exfoliated MoS2 thin films on titanium substrates have been investigat
ed by scanning tunneling microscopy (STM) and spectroscopy (STS). Sing
le layers of MoS2 Were placed on titanium substrates by an intercalati
on-exfoliation method. These layers consist of several hexagonal islan
ds of surface atoms on the basal planes as well as axial planes with d
angling bonds. The STS measurements showed a surface band gap value of
0.3 eV, which is lower than the value obtained on a single crystal of
MoS2 (0.8 eV). Thus the differential conductivity measurements indica
te that these films have a high density of states and conductivity due
to the presence of a large number of axial lanes at the interface.