In this article, we discuss the advantages of using Sb as a solvent fo
r the growth of antimony-based solid solutions. We developed the LPE g
rowth technology of InGaAsSb layers from Sb-rich liquid phases on GaSb
substrates in both sides of the miscibility gap, near GaSb and near I
nAs. A strong substrate orientation influence was found on the effecti
ve segregation coefficients of components. The InGaAsSb;GaSb structure
s were studied by double-crystal X-ray diffraction. From a study of th
e variation of the rocking curves' half-width with supercooling temper
ature, it is possible to optimize the technological growth conditions.
It is shown that high-quality InGaAsSb epitaxial layers can be produc
ed by this technique.