Ja. Floro et al., REAL-TIME STRESS EVOLUTION DURING SI1-XGEX HETEROEPITAXY - DISLOCATIONS, ISLANDING, AND SEGREGATION, Journal of electronic materials, 26(9), 1997, pp. 969-979
We have used sensitive real-time measurements of film stress during Si
1-xGex molecular beam epitaxy to examine strain relaxation due to cohe
rent island formation, and to probe the kinetics of Ge surface segrega
tion. We first describe our novel curvature-measurement technique for
real-time stress determination. Measurements of the relaxation kinetic
s during high temperature Si79Ge21 growth on Si (001) are reported in
which formation of highly regular arrays of [501]-faceted islands prod
uce 20% stress relaxation. An island shape transition is also observed
that reduces the effective stress by up to 50% without dislocations.
Nonuniform composition profiles due to Ge surface segregation during g
rowth of planar alloy films are determined with submonolayer thickness
resolution from the real-time stress evolution. Up to two monolayers
of Ge can segregate to the growth surface.