Epg. Vandenberg et al., IN-SITU TOPOGRAPHY OF THE (200)-FACE OF EPSILON-CAPROLACTAM GROWING FROM THE VAPOR-PHASE, Journal of crystal growth, 180(2), 1997, pp. 284-292
On the (2 0 0) face of epsilon-caprolactam growing from the vapour pha
se several growth phenomena were observed in situ by optical microscop
y: single spirals, multiple spirals, spirals growing with monomolecula
r steps, Vapor-liquid-solid (VLS) growth and two-dimensional nucleatio
n. From the observations and measured growth rates the relative import
ance of the volume, surface diffusion and step integration as the rate
determining step of the growth process are elaborated.