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Substituted triazines and pyrimidines from 1,3,5-triazine and a lithium amidinate, alkyl- or 1-azaallyl
Authors: Boesveld, WM Hitchcock, PB Lappert, MF
Citation: Wm. Boesveld et al., Substituted triazines and pyrimidines from 1,3,5-triazine and a lithium amidinate, alkyl- or 1-azaallyl, J CHEM S P1, (9), 2001, pp. 1103-1108
Synthesis and structures of lithium N-trimethylsilyl- and -neopentyl-anilides and their Et2O and tmen adducts; crystal structures of [(Li{mu-N(Ph)R}-trans)(2)(mu-tmen)](infinity) (R = SiMe3 1 or CH2But 2) and [Li{mu-N(Ph)CH2But}(OEt2)](2)
Authors: Bezombes, JP Hitchcock, PB Lappert, MF Merle, PG
Citation: Jp. Bezombes et al., Synthesis and structures of lithium N-trimethylsilyl- and -neopentyl-anilides and their Et2O and tmen adducts; crystal structures of [(Li{mu-N(Ph)R}-trans)(2)(mu-tmen)](infinity) (R = SiMe3 1 or CH2But 2) and [Li{mu-N(Ph)CH2But}(OEt2)](2), J CHEM S DA, (6), 2001, pp. 816-821
Synthesis and structures of crystalline dilithium diamides and aminolithium amides derived from N,N '-disubstituted 1,2-diaminobenzenes or 1,8-diaminonaphthalene
Authors: Daniele, S Drost, C Gehrhus, B Hawkins, SM Hitchcock, PB Lappert, MF Merle, PG Bott, SG
Citation: S. Daniele et al., Synthesis and structures of crystalline dilithium diamides and aminolithium amides derived from N,N '-disubstituted 1,2-diaminobenzenes or 1,8-diaminonaphthalene, J CHEM S DA, (21), 2001, pp. 3179-3188
The reactions of lithium trimethysilylmethyls with isocyanides; structuresand reactions of the derived lithium 1-azaallyls, beta-diketiminates and a1-azabuta-1,3-dienyl-3-amide
Authors: Hitchcock, PB Lappert, MF Layh, M
Citation: Pb. Hitchcock et al., The reactions of lithium trimethysilylmethyls with isocyanides; structuresand reactions of the derived lithium 1-azaallyls, beta-diketiminates and a1-azabuta-1,3-dienyl-3-amide, J CHEM S DA, (16), 2001, pp. 2409-2416
Synthesis, structures and catalytic properties of chelating N,N '-bis(silylated) 1,2-benzenediamidozirconium(IV) chlorides [and a titanium(IV) analogue] and dimethylamides
Authors: Daniele, S Hitchcock, PB Lappert, MF Merle, PG
Citation: S. Daniele et al., Synthesis, structures and catalytic properties of chelating N,N '-bis(silylated) 1,2-benzenediamidozirconium(IV) chlorides [and a titanium(IV) analogue] and dimethylamides, J CHEM S DA, (1), 2001, pp. 13-19
Cerium masquerading as a Group 4 element: synthesis, structure and computational characterisation of [CeCl{N(SiMe3)(2)}(3)]
Authors: Eisenstein, O Hitchcock, PB Hulkes, AG Lappert, MF Maron, L
Citation: O. Eisenstein et al., Cerium masquerading as a Group 4 element: synthesis, structure and computational characterisation of [CeCl{N(SiMe3)(2)}(3)], CHEM COMMUN, (17), 2001, pp. 1560-1561
Li, Al, Sn and Zr complexes of bidentate N,N '-centred ligands
Authors: Hitchcock, PB Lappert, MF Merle, PG
Citation: Pb. Hitchcock et al., Li, Al, Sn and Zr complexes of bidentate N,N '-centred ligands, PHOSPHOR SU, 168, 2001, pp. 363-366
Novel metal complexes containing 1-azaallyl and beta-diketiminato ligands
Authors: Bourget-Merle, L Hitchcock, PB Lappert, MF
Citation: L. Bourget-merle et al., Novel metal complexes containing 1-azaallyl and beta-diketiminato ligands, PHOSPHOR SU, 168, 2001, pp. 609-612
The thermally stable silylene Si[(NCH2But)(2)C6H4-1,2]: Reactions with (BuCN)-C-t, AdCN, (BuNC)-N-t, AdN(3), and Me3SiN3 (Ad=1-adamantyl)
Authors: Gehrhus, B Hitchcock, PB Lappert, MF
Citation: B. Gehrhus et al., The thermally stable silylene Si[(NCH2But)(2)C6H4-1,2]: Reactions with (BuCN)-C-t, AdCN, (BuNC)-N-t, AdN(3), and Me3SiN3 (Ad=1-adamantyl), Z ANORG A C, 627(5), 2001, pp. 1048-1054
Synthesis, properties and structures of the tris(cyclopentadienyl)thorium(III) complexes [Th{eta(5)-C5H3(SiMe2R)(2)-1,3}(3)] (R = Me or Bu-t)
Authors: Blake, PC Edelstein, NM Hitchcock, PB Kot, WK Lappert, MF Shalimoff, GV Tian, S
Citation: Pc. Blake et al., Synthesis, properties and structures of the tris(cyclopentadienyl)thorium(III) complexes [Th{eta(5)-C5H3(SiMe2R)(2)-1,3}(3)] (R = Me or Bu-t), J ORGMET CH, 636(1-2), 2001, pp. 124-129
Chemistry of thermally stable bis(amino)silylenes
Authors: Gehrhus, B Lappert, MF
Citation: B. Gehrhus et Mf. Lappert, Chemistry of thermally stable bis(amino)silylenes, J ORGMET CH, 617(1), 2001, pp. 209-223
Review of metal 1-azaallyl complexes
Authors: Caro, CF Lappert, MF Merle, PG
Citation: Cf. Caro et al., Review of metal 1-azaallyl complexes, COORD CH RE, 219, 2001, pp. 605-663
Spontaneous generation of stable pnictinyl radicals from "jack-in-the-box"dipnictines: A solid-state, gas-phase, and theoretical investigation of the origins of steric stabilization
Authors: Hinchley, SL Morrison, CA Rankin, DWH Macdonald, CLB Wiacek, RJ Voigt, A Cowley, AH Lappert, MF Gundersen, G Clyburne, JAC Power, PP
Citation: Sl. Hinchley et al., Spontaneous generation of stable pnictinyl radicals from "jack-in-the-box"dipnictines: A solid-state, gas-phase, and theoretical investigation of the origins of steric stabilization, J AM CHEM S, 123(37), 2001, pp. 9045-9053
The first crystalline alkali metal salt of a benzenoid radical anion without a stabilizing substituent and of a related dimer: X-ray structures of the toluene radical anion and of the benzene radical anion dimer potassium-crown ether salts
Authors: Hitchcock, PB Lappert, MF Protchenko, AV
Citation: Pb. Hitchcock et al., The first crystalline alkali metal salt of a benzenoid radical anion without a stabilizing substituent and of a related dimer: X-ray structures of the toluene radical anion and of the benzene radical anion dimer potassium-crown ether salts, J AM CHEM S, 123(1), 2001, pp. 189-190
Synthesis and structures of lithium, aluminium, gallium and lanthanide amidinates containing a gamma-pendant amine functionality
Authors: Doyle, D Gun'ko, YK Hitchcock, PB Lappert, MF
Citation: D. Doyle et al., Synthesis and structures of lithium, aluminium, gallium and lanthanide amidinates containing a gamma-pendant amine functionality, J CHEM S DA, (22), 2000, pp. 4093-4097
Crystalline (NN)C-M(NN) complexes: synthesis, structure, bonding and lability [M = Si, Ge, Sn or Pb; (NN)=1,2-((BuCH2N)-C-t)(2)C6H4]
Authors: Gehrhus, B Hitchcock, PB Lappert, MF
Citation: B. Gehrhus et al., Crystalline (NN)C-M(NN) complexes: synthesis, structure, bonding and lability [M = Si, Ge, Sn or Pb; (NN)=1,2-((BuCH2N)-C-t)(2)C6H4], J CHEM S DA, (18), 2000, pp. 3094-3099
Reactions of LiCHR2 and related lithium alkyls with alpha-H free nitriles and the crystal structures of eleven representative lithium 1,3-diazaallyls, 1-azaallyls and beta-diketiminates
Authors: Hitchcock, PB Lappert, MF Layh, M Liu, DS Sablong, R Shun, T
Citation: Pb. Hitchcock et al., Reactions of LiCHR2 and related lithium alkyls with alpha-H free nitriles and the crystal structures of eleven representative lithium 1,3-diazaallyls, 1-azaallyls and beta-diketiminates, J CHEM S DA, (14), 2000, pp. 2301-2312
Synthesis and structures of 1,3,5,7-tetraazaheptatrienylsodium and -thallium(I)
Authors: Boesveld, WM Hitchcock, PB Lappert, MF Noth, H
Citation: Wm. Boesveld et al., Synthesis and structures of 1,3,5,7-tetraazaheptatrienylsodium and -thallium(I), ANGEW CHEM, 39(1), 2000, pp. 222-224
Thermal condensation of trinuclear lanthanide butoxides. Molecular structure of La-5 (mu(5)-O) (mu(3)-(OBu)-Bu-t)(4)(mu-(OBu)-Bu-t)(4)((OBu)-Bu-t)(5)
Authors: Daniele, S Hubert-Pfalzgraf, LG Hitchcock, PB Lappert, MF
Citation: S. Daniele et al., Thermal condensation of trinuclear lanthanide butoxides. Molecular structure of La-5 (mu(5)-O) (mu(3)-(OBu)-Bu-t)(4)(mu-(OBu)-Bu-t)(4)((OBu)-Bu-t)(5), INORG CH C, 3(5), 2000, pp. 218-220
Persistent phosphinyl radicals from a bulky diphosphine: an example of a molecular jack-in-the-box
Authors: Hinchley, SL Morrison, CA Rankin, DWH Macdonald, CLB Wiacek, RJ Cowley, AH Lappert, MF Gundersen, G Clyburne, JAC Power, PP
Citation: Sl. Hinchley et al., Persistent phosphinyl radicals from a bulky diphosphine: an example of a molecular jack-in-the-box, CHEM COMMUN, (20), 2000, pp. 2045-2046
The diverse reactions of the silylene Si[(NCH2But)(2)C6H4-1,2] with Li[Si(SiMe3)(3)](thf)(3) and K[N(SiMe3)(2)]
Authors: Gehrhus, B Hitchcock, PB Lappert, MF Slootweg, JC
Citation: B. Gehrhus et al., The diverse reactions of the silylene Si[(NCH2But)(2)C6H4-1,2] with Li[Si(SiMe3)(3)](thf)(3) and K[N(SiMe3)(2)], CHEM COMMUN, (15), 2000, pp. 1427-1428
Unusual alkali metal alpha- or beta-phenyl(trimethylsilyl)amides
Authors: Antolini, F Hitchcock, PB Lappert, MF Merle, P
Citation: F. Antolini et al., Unusual alkali metal alpha- or beta-phenyl(trimethylsilyl)amides, CHEM COMMUN, (14), 2000, pp. 1301-1302
Synthesis and structural characterisation of new ansa-bis(propene)s and {ansa-bis(allyl)}alkali metal and {ansa-bis(allyl)}transition metal complexes
Authors: Fernandez-Galan, R Hitchcock, PB Lappert, MF Antinolo, A Rodriguez, AM
Citation: R. Fernandez-galan et al., Synthesis and structural characterisation of new ansa-bis(propene)s and {ansa-bis(allyl)}alkali metal and {ansa-bis(allyl)}transition metal complexes, J CHEM S DA, 11, 2000, pp. 1743-1749
Synthesis and structures of the crystalline heavier alkali metal alkyls: X-ray structures of [K(mu-R){O(Me)Bu-t}](infinity), [(pmdeta)K(mu-R)K(mu-R)(2)K(mu-R)K(pmdeta)], and [Cs(mu-R)(tmeda)]infinity (R = CH(SiMe3)(2))
Authors: Boesveld, WM Hitchcock, PB Lappert, MF Liu, DS Tian, S
Citation: Wm. Boesveld et al., Synthesis and structures of the crystalline heavier alkali metal alkyls: X-ray structures of [K(mu-R){O(Me)Bu-t}](infinity), [(pmdeta)K(mu-R)K(mu-R)(2)K(mu-R)K(pmdeta)], and [Cs(mu-R)(tmeda)]infinity (R = CH(SiMe3)(2)), ORGANOMETAL, 19(20), 2000, pp. 4030-4035
Lanthanocene chemistry with [Cp-R](-), [Cp-t](-), [Cp-tt](-), and [(Cp2SiMe2)-Si-R '](2-) ligands: Synthesis and characterization of bis(cyclopentadienyl)lanthanide(III) halides and bis(cyclopentadienyl)lanthanide(II) complexes and crystal structures of [{NdCp2R(mu-Cl)}(2)], [{TmCp2tt(mu-I)}(2)], and [Yb((Cp2SiMe2)-Si-R ')(THF)(2)] (Cp-R = eta(5)-C5H4{CH(SiMe3)(2)}, Cp-t = eta(5)-C5H4(SiMe2But), Cp-tt = eta(5)-C5H3(SiMe2But)(2)-1,3, and Cp-R ' =eta(5)-C5H3{CH(SiMe3)(2)}-3)
Authors: Hitchcock, PB Lappert, MF Tian, S
Citation: Pb. Hitchcock et al., Lanthanocene chemistry with [Cp-R](-), [Cp-t](-), [Cp-tt](-), and [(Cp2SiMe2)-Si-R '](2-) ligands: Synthesis and characterization of bis(cyclopentadienyl)lanthanide(III) halides and bis(cyclopentadienyl)lanthanide(II) complexes and crystal structures of [{NdCp2R(mu-Cl)}(2)], [{TmCp2tt(mu-I)}(2)], and [Yb((Cp2SiMe2)-Si-R ')(THF)(2)] (Cp-R = eta(5)-C5H4{CH(SiMe3)(2)}, Cp-t = eta(5)-C5H4(SiMe2But), Cp-tt = eta(5)-C5H3(SiMe2But)(2)-1,3, and Cp-R ' =eta(5)-C5H3{CH(SiMe3)(2)}-3), ORGANOMETAL, 19(17), 2000, pp. 3420-3428
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