K. Ino et al., PLASMA-ENHANCED IN-SITU CHAMBER CLEANING EVALUATED BY EXTRACTED-PLASMA-PARAMETER ANALYSIS, IEEE transactions on semiconductor manufacturing, 9(2), 1996, pp. 230-240
We have demonstrated that high-efficiency in situ chamber cleaning wit
h short gas residence time is possible for SiO2 etching chambers by us
e of NF3 plasma, and that the endpoint determination of the cleaning i
s possible by monitoring the optical emission intensities of CO or H.
Nitrogen trifluoride (NF3), which has a low N-F bond energy, can gener
ate a plasma with a high density of ions and radicals featuring low ki
netic energy, The cleaning efficiency of several halogenated-gas plasm
as has been evaluated based on extracted-plasma-parameter analysis. In
this analysis important plasma parameters, such as ion energy and ion
flux density, can be extracted through a simple rf waveform measureme
nt at the plasma excitation electrode. The accuracy of this technique
has been confirmed with a newly developed rf-plasma direct probing met
hod and by ion current measurements.